Reddit reviews Liquid Creosote Remover - Anti-Creo-Soot | 1 Gallon Bottle | Removes Dangerous Glazed Creosote and Soot
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Regular Use of Liquid ACS Converts Hazardous Creosote to a Harmless Ash or Char, Making it Easier to Remove by Chimney SweepingImproves Efficiency of Wood and Coal Stoves, Furnaces, and Boilers by Making it Easier to Removing Creosote and Soot Build UpChimneys Clean Easier and More CompletelyReduces Creosote Odors and PollutionNon-Toxic and Easy to Use - Daily Use During the Heating Season Reduces & Helps Eliminate Glazed Creosote Buildup
Yes, it is tar and other residue left behind by the wood. It is black and sticky when fresh, and dries out glazed and rock hard. You can use a creosote remover, if you wish. There are many out there; this is the one I use. I put in in a spray bottle, and use it twice, three times a week during the cold months:
https://www.amazon.com/Liquid-Creosote-Remover-Anti-Creo-Soot-Dangerous/dp/B004SICUIK
For me, one gallon lasts about three years.